Polymer films on electrodes. 21. Electrochemical behavior of tetramethyltetraselenafulvalene incorporated into a Nafion-coated electrode
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چکیده
The cyclic voltammetry of tetramethyltetraselenafulvalene (TMTSF) in CH2CI2 is described. Controlled potential coulometry yielded a suspension of (TMTSF)zCIO4 crystals. The incorporation of TMTSF onto a Pt electrode coated with the perfluorinated ion exchange polymer Nation and the electrochemical behavior of the electrode in aqueous NaCIO4 is described and compared to the related compound tetrathiafulvalene (TIT). A pair of peaks separated by about 400 mV is observed and is ascribed to the couple TMTSF/(TMTSF)~ClOg. However, formation of the needle-like crystals found with Nation/TIT was not seen with TMTSF.
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تاریخ انتشار 2008